The multilevel coding technique is a powerful method for constructing coding schemes from component codes in conjunction with set partitioning of coset code. The concatenated coding can construct long block codes from short component codes. In this thesis, an Reed-Solomon(RS)-concatenated multilevel coding scheme is proposed. By concatenating an outer Reed-Solomon code with an inner interlevel-correlated multilevel coset codes , the concatenated coding scheme can achieve large coding gain and low decoding complexity. Simulation results show that the proposed coding scheme outperforms Low-Density Parity-Check(LDPC) codes at low signal-to-noise ratio.