Organic materials have attracted a lot of attention recently years such as Organic light-emitting diodes, Organic solar cells, Organic thin-film transistors and Organic bistable memory devices. This article is studied about organic bistable memory devices based on the Poly(arylether)s. This polymer is used to make a device of sandwich structure, organic films between two metals. The current-voltage characteristics show that the device switches from the initial Low-conduction to High-conduction when we used external electric field. The different state can be used as binary “0” and “1”.