奈米光電高分子材料之研究

The study of nano-photoelectronic polymer materials

林守志(Shou-Chih Lin)

指導教授 ： 廖義田

國立臺北科技大學/工程學院/有機高分子研究所/碩士(2012年)

摘要

使用不同方式的電聚合共軛導電高分子，並參考其他文獻,研究如何將在一固體基材上製作出具有微圖案的排列的產物，期望能在導電玻璃上創造具有微圖案排列的導電高分子。目的是希望研究出低成本的製程，應用在有機微電子元件上。本實驗利用光學顯影和化學蝕刻的方式，製作出具有微流道的模版，再利用電鑄鎳的方式，製作出鎳金屬模版。之後使用PDMS翻製法，將PDMS單體均勻倒在鎳模版上，並放入的烘箱中以80˚C 烘烤8小時使其硬化。之後分離鎳模板和PDMS薄膜，即可得到具微流道的矽膠膜。之後覆蓋在導電玻璃上和共軛高分子單體電聚合，最終得到具大面積微圖案排列的導電高分子。

關鍵字

共軛高分子 ； 電聚合 ； 微圖案

並列摘要

In this study, A different process is used to carry out electropolymerization of conjugated polymers. Micropatterns of conjugated polymers on solid substrates and manipulated to be applied in optoelectronics industries. This experiment develops a different strategy for the preparation of conductive polymers micropatterns on ITO substrates. The purpose is to produce low-cost organic microelectronic devices.
Photolithography techniques are used to create a microchannel polymer plate. PDMS monomer is applied on the nickel template, and heated for 8 hours at 80 C . After The microchannels were constructed by firmly placing an appropriate PDMS mold with microtrenches onto an ITO surface. Preparation of large-area micropatterns is created by electropolymerization of conjugated polymers within microchannels. The final micropatterns of conductive polymers on ITO substrates are obtained.

並列關鍵字

conjugate polymers ； electropolymerization ； micropattern

參考文獻

[32]徐玄修、林永昇、殷宏林、謝哲偉，生醫微流體晶片之製程平台，儀器科技研究中心。

[2]胡瑞宏，共軛高分子及光電材料之合成，碩士論文，國立臺北科技大學有機高分子研究所，台北，2006。

[6]B. Wessling, 1991, Synth. Met., Vol 1, p. 119.

[8]Yiqing Lu, Guangxia Shen, Chongjun Zhao, Shouwu Guo, Fabrication of polypyrrole micropatterns through microchannel-confined electropolymerization and their electrical conductivities , Electrochimica Acta 54 (2009) 4253–4257.

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