In the two-way relay networks with two relays between two nodes, the previous scheme proposed a two-way relay network coding system using all Decode-and-Forward (DAF) elements without STBC. In our proposed scheme, we transmit using Alamouti DSTBC with adaptive AAF/DAF elements. The simulation result shows that at 10-2 BER our proposed scheme is better than the previous scheme by 1.2dB,1.8dB,2dB and 2.2dB forδ = 2,1.44,1 and 0.8, respectively.