The object this research is to formulate a polymeric photoresist used as a solder mask in printed circuit board that has the good developable property, resolution, and soldering resistance. The effects of variables in polymerizing the binder such as the polymerization temperature, the relative amount of constituents, and the initiator content on the performance of the photoresist are studied. The results of tests indicate that with the proper formulation and the use of binder with a molecular weight of 25000~32000 and an acid value near 67~78, the formulated solder mask have a great resolution and developable property. The adhesion strength, soldering resistance, surface hardness, and appearance of the final product all meet the industrial standards.