透過您的圖書館登入
IP:52.15.112.69
  • 學位論文

向列型液晶(E7)相變化黏滯係數之研究

Studying on the viscosity coefficient of nematic liquid crystal (E7) at the phase transition

指導教授 : 周勝次
若您是本文的作者,可授權文章由華藝線上圖書館中協助推廣。

摘要


本論文主要是研究向列型液晶(E7)在變溫過程中黏滯係數的變化量測,實驗上主要是藉由偏光顯微鏡與示差熱掃描分析儀測定液晶相變點溫度,並使用圓錐-平板式黏度計量測溫變時液晶黏滯係數,同時藉由偏光顯微鏡觀察液晶(E7)隨溫度變化時相變的行為、發現相變狀態是一連續非均勻的混合態變化,並探討其黏滯係數與溫度之關係,經由本實驗結果發現,液晶(E7)的相變是經過一個與溫度有關的範圍,而不是一般物質的單一相變點,此種現象從未被證實過。

並列摘要


In this thesis, we investigated the viscosity coefficient of liquid crystal (LC) - E7, with its temperature dependence. In the experiment, we used the polarizing optical microscopy (POM) and Differential Scanning Calorimeter (DSC) to monitor the transition process of liquid crystal. To study the transient behavior of E7, we used the Cone and Plate Viscosmeter to measure the temperature-dependent viscosity coefficient. The POM experimental results show that the phase transition of E7 is a continuous and nonhomogeneous phenomenon depending on the temperature. According to the result, we could analyze the relationship of viscosity coefficient and temperature by calculating the volume ratio in the different states. We found the there is a window for phase transition process of E7, but not a critical temperature point. This result is a new finding and different from any previous investigations. This research will give important information to the fundamental understanding of the phase transition of LC.

並列關鍵字

Liquid Crystal POM DSC Viscosity

參考文獻


[1] A. Chrzanowska and K. Sokalski, “Microscopic description of nematic liquid crystal viscosity.,” Phys. Rev. E, Vol 52, Num 5, 1995.
[2] S. Meiboom and R. C. Hewitt, “Measurements of the Rotational Viscosity Coefficient and the Shear-Alignment Angle in Nematic Liquid Crystals,” Phys. Rev. Lett., Vol 30, Num 7, 1973.
[3] A. V. Zakharov, A. V. Komolkin and A. Maliniak, “Rotational viscosity in a nematic liquid crystal: A theoretical treatment and molecular dynamics simulation,” Phys. Rev. E, Vol 59, Num 6, 1999.
[4] A. V. Zakharov and Y. Ronald Dong, “Rotational viscosity, dynamic phenomena, and dielectric properties in a long-chain liquid crystal: NMR study and theoretical treatment,” Phys. Rev. E, Vol 63, pp. 011704, 2000.
[5] M. Vilfan, I. Drevensek Olenik, A. Mertelj and M. Copic, “Aging of surface anchoring and surface viscosity of a nematic liquid crystal on photoaligning poly-(vinyl-cinnama),” Phys. Rev. E, Vol. 63, pp. 061709, 2001.

延伸閱讀