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  • 學位論文

使用含鐵碳管快速過濾亞甲基藍

Rapid removal of methylene blue by Fe-filled CNTs

指導教授 : 徐文光

摘要


本實驗以含鐵奈米碳管做為快速過濾亞甲基藍之載體。經由化學氣相沈積法合成之含鐵碳管吸附汙染物質之後,利用磁鐵將含鐵碳管從溶液中快速分離,減少過濾時間。XRD,SEM和TEM分析顯示碳管內α-鐵為主要結構而雪明碳鐵、三氧化二鐵為次要結構。超導量子干涉儀證明含鐵碳管具鐵磁性,其飽和磁化量高達0.85emu。UV光譜儀所得亞甲藍液的濃度變化證實了含鐵碳管能夠成為有機物吸附之載體。經由拉曼光譜儀證實六連環之缺陷也是吸付機制之一。

並列摘要


Carbon nanotubes (CNTs), due to surface ring currents and high specific surface area, are often used as absorbing materials and energy storage devices. This thesis focuses on use of Fe-filled CNTs as adsorbents for simultaneous filtering of methylene blue in solution. Fe-filled CNTs are made by pyrolysis of ferrocene and core structure, as revealed by XRD, SEM and TEM, is dominated by α-Fe, along with Fe3C and Fe2O3 as minority. SQUID indicate that Fe-filled CNTs are of ferromagnetic and saturation magnetization reaches a value as high as 0.85emu. UV-Vis spectrometric data confirm reduced concentration of methylene blue by Fe-filled CNTs and the adsorption mechanism resulting from the defects of hexagonal carbon network through Raman spectrometer.

並列關鍵字

無資料

參考文獻


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