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  • 學位論文

ZnTe/ZnSe量子點的光學特性研究

Optical studies of ZnTe/ZnSe quantum dots

指導教授 : 沈志霖
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摘要


本文研究Ⅱ-Ⅵ ZnTe/ZnSe量子點的光學特性,其能帶結構屬於型態II異質結構。我們利用光激螢光與時間鑑別光激螢光,在不同的激發功率與溫度下研究其特性。當雷射激發光功率增強時,由於能帶會彎曲,使得螢光峰值有明顯的藍位移。光激螢光的半高寬隨著溫度增加有先變窄再變寬的趨勢代表載子會藉由濕層結構作橫向轉移到其他量子點。我們以單指數加延伸指數完美的擬合出量子點的螢光衰減圖形,得到了兩個載子生命期,即時間較短的τ1與時間較短的τ2。隨著激發功率的增加,τ1會因為電子電洞波函數重疊增加而變短;τ2則會因為載子作橫向轉移的數目增加而變長。

並列摘要


The optical properties of the self-organized type-II ZnTe/ZnSe quantum dots are studied by photoluminescence (PL) and time-resolved PL under different excitation intensities and temperatures. A blue shift of the quantum-dot peak is observed in the power-dependent PL due to the band-bending effect. The full width at half maximum (FWHM) of PL reduces firstly then broadens with increasing temperature, revealing a signature of the carrier lateral transfer. The time-resolved PL signal is well fitted by the combination of a single exponential and a stretch-exponential function, whose carrier lifetime is corresponding to τ1(shorter lifetime) and τ2(longer lifetime), separately. The carrier lifetime of τ1 decreases with increasing excitation intensity due to the increase of the overlap between electron and hole wavefunctions. On the other hand, τ2 increases with excitation intensity, resulting from the increase of the lateral carrier transfer.

並列關鍵字

ZnTe TRPL PL quantum dots

參考文獻


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被引用紀錄


許喆閎(2008)。有機高分子Ph-LPPP在高壓下的光致螢光〔碩士論文,淡江大學〕。華藝線上圖書館。https://doi.org/10.6846/TKU.2008.00078

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