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  • 學位論文

多鐵材料GdMn2O5之結構與電性交互作用研究

Study of interplay between sturcture and electrical properties of multiferroic GdMn2O5 nanorods

指導教授 : 楊仲準
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摘要


本研究利用水熱法製作GdMn2O5奈米棒樣品。以不同溫度的熱退火來改變奈米棒的尺寸。樣品分別以X光粉末繞射儀、電性量測系統儀器,對於結構和介電系數等方面進行相關分析與論探討。 本研究中,X光繞射所得到的結構精算顯示,當ξc=80 nm時,在26 K的錳氧鍵長有一個異常突變。另外一方面,變溫高頻的介電係數量測與變溫X光繞射之出現異常繞射峰之溫區相符。這顯示了臨界尺寸會造成錳氧鍵長的突變,進而影響磁電交互作用。其發生磁電交互作用的臨界尺寸介於ξc=80 nm到60 nm之間。

並列摘要


In this study, hydrothermal method was employed to synthesis the GdMn2O5 nanorods. Different rod sizes were growth by annealing procedure in different temperature. X-ray and electrical measurements system were used to characterize characteristic the crystal structure, dielectric constant of these obtained samples. The x-ray diffraction results show an unusual variation of Mn-O bond at 26 K in 80 nm sample. On the other hand, variable-temperature high-frequency dielectric measurement system and x-ray diffraction have the same result, This implies that the Magnetoelectric coupling is controlled by the size effect. And the critical size of GdMn2O5 nanorods is in between 80 and 60 nm along c axis.

參考文獻


[15] 翁誠佑, 釓錳氧化物奈米棒之尺寸效應研究, 中原大學碩士論文 (2010)
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[7] L.Solymer and D. Walsh, Electrical Properties of Materials, 218-221 (1998)
[8] Arthur R. Von Hipple, Dielectrics and Waves, 3-6 (1966)

被引用紀錄


林亮劼(2017)。稀土錳氧化物奈米棒之尺寸效應與介電性質研究〔碩士論文,中原大學〕。華藝線上圖書館。https://doi.org/10.6840/cycu201700646

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