本論文探討下列化合物之合成與結構: [Co(L1)(MeOH)4](ClO4)2•(MeOH)∞ [L1 = N,N´-di-(3-pyridyl)adipoamide], 1; [Cu2(HL2)4(ClO4)2](ClO4)2 (HL2 = 2-Aminonicotinic acid),2;[Cu2(HL2)4(BF4)2](BF4)2•2H2O,3與 [Ag(L2)]∞,4。以上四種化合物均利用元素分析儀、紅外光光譜儀、熱重分析儀和螢光光譜儀鑑定分析特性,並以單晶 X-ray 繞射儀鑑定其結構。 在化合物1 中,鏈與鏈之間藉由陰離子以N-H---O氫鍵作用力連接形成二維層狀結構。化合物2與3 皆形成雙核分子且利用N-H---O、C-H---O、N-H---F與C-H---F氫鍵作用力形成三維超分子結構。在化合物4中,其L2配位基以μ3- η1: η1: η1配位模式與金屬鍵結形成具有(82,10)拓墣構型的三維結構。
This thesis discusses the synthesis and structures of [Co(L1)(MeOH)4](ClO4)2•(MeOH)∞ [L1 = N,N´-di-(3-pyridyl)adipoamide], 1; [Cu2(HL2)4(ClO4)2](ClO4)2 (HL2 = 2-Aminonicotinic acid), 2; [Cu2(HL2)4(BF4)2](BF4)2•2H2O, 3 and [Ag(L2)]∞, 4 . All the complexes have been characterized by EA, IR, TGA and PL, and structurally characterized by X-ray crystallography. In complex 1, the 1D zigzag chains are interlinked by the anions through the N-H---O hydrogen bonds to form a 2D layer structure. Complexes 2 and 3 show the dimeric structures and their molecules are interlinked though a series of N-H---O, C-H---O, N-H---F and C-H---F hydrogen bonds to form 3D supramolecular archetures. In complex 4, the L2 ligand shows μ3- η1: η1: η1 bonding mode which link the metal atoms to form a 3D structure with (82,10) topology.