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  • 學位論文

層化高分子/液晶複合薄膜的介電特性

Dielectric Properties of Stratified Polymer–Liquid-Crystal Composite Films

指導教授 : 李偉

摘要


本論文聚焦於液晶與高分子聚合物層間的相互作用,探討高分子/液晶複合系統的介電特性。對於上述結構,吾人藉由相分離複合薄膜的技術來簡化複雜的研究對象,其成果即為層化高分子/液晶複合薄膜。本研究利用介電頻譜術來分析在不同環境溫度以及光聚合程度下的各種極化行為,為了深入探討複合系統中所特有的介面極化,吾人引用濃差極化層的概念來描述在界面處的電荷累積行為。由於介面極化的鬆弛頻率暗示著具有兩已知介電常數介質的複材結構,因此能在不損壞液晶盒的狀態下,用以求得分層結構中的液晶層厚度;該技術可進而發展成為非破壞性之薄膜厚度量測法。

關鍵字

介面極化 介電頻譜 高分子

並列摘要


This thesis focuses on the interplay between liquid crystal and polymer layers, exploring the dielectric properties of the polymer/liquid-crystal composite system. We adopt the phase-separated composite film (PSCOF) technique to simplify the complicated system, the result is a stratified polymer/liquid crystal composite film. This study exploits the dielectric spectroscopy to analyze various polarization behaviors under different environmental temperatures and photo-polymerization states. To investigate the interface polarization being specifically exhibited in the composite system, the concept of concentration polarization layer has been introduced to describe the charge-cumulative behaviors at the interface. The relaxation frequency of the interface polarization sheds light on the structure of the composites with two components of given dielectric constants, which enables one to roughly calculate the thickness of the liquid-crystal layer in PSCOF without destroying the cell, which could be further developed as a technique of non-destructive in-situ thickness measurement in a phase-separated composite.

參考文獻


[15] 簡伯儒,《液晶摻雜奈米碳管之介電研究》,碩士論文,中原大學應用物理研究所,民99年7月。
[16] 劉軒宏,《摻雜不同維度奈米粒子液晶之時變介電特性》,碩士論文,中原大學應用物理研究所,民99年7月。
[1] J. W. Doane, N. A. Vaz, B. G. Wu, and S. Žumer, “Field controlled light scattering from nematic microdroplets,’’ Applied Physics Letters 48(4), 269–271 (1985).
[2] V. Vorflusev, and S. Kumar, “Phase-separated composite films for liquid crystal displays.” Science 283, 1903–1905 (1999).
[3] 黃文賢,《添加探奈米管之高分子聚合物穩定型液晶元件的光電特性》,碩士論文,中原大學應用物理研究所,民95年1月。

被引用紀錄


陳建璋(2013)。含高分子與液晶雙層膜之一維光子結構的穿透光譜〔碩士論文,中原大學〕。華藝線上圖書館。https://doi.org/10.6840/cycu201300784
林威廷(2012)。高分子分散型液晶之介面極化〔碩士論文,中原大學〕。華藝線上圖書館。https://doi.org/10.6840/cycu201200550

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