以菲啶為核心之可用於鈣鈦礦太陽能電池的電洞傳輸層材料

Phenanthridine-based Hole-Transporting Materials for Perovskite Solar cells

林俊呈(JUN-CHENG LIN)

指導教授 ： 嚴詠聖

中原大學/理學院/化學系/碩士(2022年)

https://doi.org/10.6840/cycu202201295

摘要

本篇論文利用鈀金屬催化之碳-氮鍵耦合反應、Suzuki Miyaura 反應，成功合成出四種以 6-alkoxylphenanthridine 為核心的化合物，利用不同的推電子基團調控分子化合物的能階，得到這一系列的化合物 6-alkoxylphenanthridine (JAS) 系列的化合物。

為了瞭解 JAS 系列化合物的性質，我們利用 TGA、DSC 測量其熱穩定性，分光光度計與螢光光譜儀測量光物理性質，利用循環伏安特安培儀量測氧化還原電位，用以計算 JAS 系列化合物的 LUMO 及 HOMO 能階，進而探討 JAS 系列化合物對於鈣鈦礦太陽能電池電洞傳輸層的應用性。

關鍵字

以菲啶為核心之可用於鈣鈦礦太陽能電池的電洞傳輸層材料

並列摘要

There are four kinds of compounds with 6-alkoxylphenanthridine as the core were successfully synthesized by using palladium metal-catalyzed carbon-nitrogen bond coupling reaction and Suzuki Miyaura reaction, and the energy levels of molecular compounds were controlled by different electron pushing groups, and 6-alkoxylphenanthridine (JAS) series compounds were obtained.

In order to know the properties of JAS series compounds, we use TGA and DSC to measure their thermal stability, spectrophotometer and fluorescence spectrometer to measure photophysical properties, and cyclic voltammetry to measure redox potential to calculate JAS series compounds. The LUMO and HOMO energy levels were obtained, and the applicability of JAS series compounds to the hole transport layer of perovskite solar cells.

並列關鍵字

Phenanthridine-based Hole-Transporting Materials for Perovskite Solar cells

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