雙金屬錯合物催化氮烯插入反應之研究

Bimetallic Complexes Catalyzed Nitrene Insertio n

許熙恩(HSI-EN HSU)

指導教授 ： 莊敬

中原大學/理學院/化學系/碩士(2022年)

https://doi.org/10.6840/cycu202201469

摘要

本研究目標為探討添加不同含氮配位基，嘗試用一個簡單的辦
法來提升催化效率。透過添加不同含氮配位基，比較銠金屬催化劑
Rh2(OAc)4 進行分子間環烯類氮烯插入反應之催化效率差異。
另一個研究方向為，跳脫雙羧酸配位基思路，開發含雙1,8-萘
啶環狀結構配位基，並螯合上金屬，形成錯合物後，嘗試分子內氮
烯插入反應。並鑑定新錯合物結構。

關鍵字

雙金屬錯合物

並列摘要

The target of this study is exploring the addition of different nitrogencontaining
ligands and using a simple method to improve the catalytic
efficiency. By adding different nitrogen-containing ligands, the difference
in catalytic efficiency of rhodium metal catalyst Rh2(OAc)4 for
intermolecular nitrene insertion reaction was compared.
The other research direction is developing ligands containing
bis-1,8-naphthyridine ring structure instead of dicarboxylic acid ligands.
After ligands chelate metals to form complexes, intramolecular nitrene
insertion reactions are attempted. We identify these new complexes
structure.

並列關鍵字

Bimetallic Complexes

參考文獻

參考文獻

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4 Tak, R. K.; Amemiya, F.; Noda, H.; Shibasaki, M., Generation and application of Cu-bound alkyl nitrenes for the catalyst-controlled synthesis of cyclic β-amino acids. Chem. Sci. 2021, 12, 7809 – 7817.