Three different types of synthetic organic polymer; amine-terminating Mannich oligomers (AMO), poly(methacrylic acid) (PMAA) and poly(methyl methacrylate) (PMMA) were introduced into the inorganic lattice to form nano-composite. The AMO and PMMA were intercalated under specific conditions to achieve exfoliation of layers. PMMA/AIBN /ME-100 nano-composite complexed was coated on zinc plate to test its corrosion protection effect which showed a decrease in the corrosion current from 5.01× 10-6 μA /cm2 to 6.24 × 10-8 μA /cm2 besides increase in the polarization resistance from 3.2 kΩ.cm2 to 2.40 × 102 kΩ.cm2.