在本論文中,我們成功的用Suzuki coupling將紫質與架橋取代基合成一個大環結構,紫質大環與C60的衍生物可以藉由自組裝的方式形成Host-Guest形態,利用UV-Vis光譜觀察紫質大環,並比較紫質大環與C60衍生物自組裝後的錯合物光譜變化以及計算其形成常數。 循環伏安法可觀察紫質大環的氧化還原電位,同時觀察自組裝所形成的錯合物其氧化還原電位及還原部分錯合物能夠容納的電子數,將可應用於電子儲存的系統。
In this study, we used a MPTA bridged unit and free based porphyrin to construct a macrocyclic structure by using Suzuki coupling method. The macrocyclic porphyrin and C60 can form Host-Guest complexes by self-assembly. By using UV-Vis spectrometry, the spectral changes of the complexes can be observed and the formation constant also calculated. The redox potentials of macrocyclic porphyrin and the electron storage of the Host-Guest complexes in the reduction part can be observed by using cyclic voltammetry. It can be applied to the electronic storage system.