The work explores the mechanism of clock synchronization with Low-Power WiFi. We adopt Network Time Protocol (NTP) on Low-Power WiFi devices which combines a Universal Asynchronous Receiver/Transmitter (UART) program and a clock request program to exchange information for clock synchronizing. The approach proposed in this work can lead to a clock synchronizing mechanism with low cost and high accuracy.. Furthermore, this approach does not require an expensive development kit, so it can save the cost of the equipment expenditures.