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  • 學位論文

微波輔助合成各種石墨烯量子點的初步探討

Preliminary Study of the Microwave Assisted Synthesis of Various Graphene Quantum Dots

指導教授 : 傅傳博

摘要


本篇論文主要是研究微波反應器輔助合成各種石墨烯量子點,首先比較使用傳統方法與微波輔助合成的石墨烯量子點其螢光性質,確認微波合成的可行性;接著嘗試合成不同摻雜的石墨烯量子點,探討其最適化合成條件、表面官能基、螢光特性及量子產率等等。

並列摘要


This thesis is mainly about the microwave-assisted synthesis of various graphene quantum dots (GQDs). In order to confirm the feasibility of the microwave-assisted method, we investigated the photoluminescence properties of GQDs with traditional method and microwave-assisted method. After that, we tried to synthesize various elements doped GQDs. And then, the optimized conditions, functional groups, photoluminescence properties and quantum yields of the doped GQDs were studied.

參考文獻


1. Garg, B., T. Bisht, and Y.C. Ling, Graphene-based nanomaterials as heterogeneous acid catalysts: a comprehensive perspective. Molecules, 2014. 19(9): p. 14582-614.
2. Benitez-Martinez, S., A.I. Lopez-Lorente, and M. Valcarcel, Graphene quantum dots sensor for the determination of graphene oxide in environmental water samples. Analytical Chemistry, 2014. 86(24): p. 12279-84.
3. Gawande, M.B., et al., Microwave-assisted chemistry: synthetic applications for rapid assembly of nanomaterials and organics. Accounts of Chemical Research, 2014. 47(4): p. 1338-48.
4. Wan, X., Y. Huang, and Y. Chen, Focusing on energy and optoelectronic applications: a journey for graphene and graphene oxide at large scale. Accounts of Chemical Research, 2012. 45(4): p. 598-607.
5. 量子局限效應 (Quantum confinement effect). Available from: https://www.ansforce.com/post/S1-p781.

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