This research is about the 35th IChO competition. There are three purposes, first, to investigate the significant difference of three different channels and two different background of 35th IChO Taiwan’s study and selection camp .Secondly, we analyze the relative percentage of 35th IchO in four fields and theoretical tasks syllabus as well as the results of four competitors. Finally, the problem-solving activities of four competitors are explored based on declarative knowledge, chemical concepts and procedural knowledge . We conclude as below: I. Willian’s Creativity Assessment Packet was used to study the significant difference of three different channels of 35th IChO Taiwan’s study and selection camp. It revealed that (1) The originality and chemistry achievement of student candidates from gifted classes are notable better than those from normal classes. (2)The chemistry achievement of the student candidates enrolled by Taiwan senior high school chemistry competition winners is notably better than the other groups. (3). The fluency of the group enrolled by primary selection two-hours written test is notable better than that of the group from Taiwan senior high school chemistry competition winners. II. Secondly, the results are as follows (1).The characteristic of 35th IChO theoretical tasks is to contain the separate general chemistry test questions. Besides, the field of the most weighted percentage is physical chemistry, 34.4%. The four competitors all got high scores in general chemistry field and the average is 96.7%. Obviously, this section is not the key point to winning or losing in this competition. Three of these tasks about quantum chemistry、refrigerant and NMR spectrum are well done by the four .They gain full marks. The lowest score four competitors gained is the two tasks concerning momentum、peptide synthesis ,which could be interpreted that they are not familiar with the concepts of this field. III. Finally, it can be concluded as: (1) The achievement of solving problem of the four competitors is related to whether they master the concepts or not .The results they gained have nothing to do with the types of relevant chemical concepts. Besides, the result of only one competitor is related to concept density and the other three are not. (2) This research concludes 27 types of procedural knowledge in chemistry problem-solving. (3) The major procedural knowledge of the failure in problem solving is “to define concepts”, which suggests chemical concepts is everything.