The preparation of polysubstituted pyrazoles and their derivatives is a very important part of the synthesis of natural materials and the pharmaceutical industry. Compared with previous studies, we synthesized pyrazole in mild condition rather than harsh conditions. binaphthol phosphate, an organic catalyst with Bronsted acid properties and hydrogen bonding effect, is utilized. 2-hydroxyphenyl hydrazine which is easily obtained from the laboratory reaction with various functionalized propylene acetates featuring the electron-withdrawing group. Performing aza-Michael reaction and cycloaddition reaction yielded a polysubstituted pyrazole compound. The reaction is greatly affected by the stereo effect of the functional group, and the yield has a good performance (46-85%). Catalytic reaction was carried out in 5 mol% of binaphthol phosphate in methanol at a normal temperature.