For safety and pleasant city out looking reasons, the underground-type transmission/distribution system was widely adopted by TPC in recent years. Especially more and more 69kV~345kV level electricity power by HV underground power cables are supplied to city center through connection stations. The connection technique becomes an important topic of power system reliability. This thesis focuses on the 161 XLPE underground power cables. Firstly, the structure of power cable and electric stress are studied. Then the connection method for terminations of power cables is introduced. Finally, the COMSOL package is used to simulate the electric stress of termination of power cables.