Mn-doped GaN has been known as a promising candidate for dilute magnetic semiconductor (DMS) working at room-temperature. However, the carrier-mediate ferromagnetism is still under debate unlikely in Mn-doped GaAs. In this work, electron spin dynamics in GaN and Mn-doped GaN were investigated by time-resolved Kerr rotation (TRKR) spectroscopy, which plays an important role in transferring spin information between different Mn atoms. With the increasing Mn concentration, the electron spin shows a shorter lifetime and a larger g factor. In particular, the g factor exhibits a linear dependence on the Mn concentration, which is caused by interacting with more Mn atoms in unit volume. The s-d exchange energy N0α = 0.35 eV is determined by fitting procedure.