Measurements of Zγ production cross section in proton-proton collisions at √s =7 TeV are presented. The results are based on data recorded by the CMS detector at the LHC that correspond to an integrated luminosity of 5.0 fb−1. The cross sections are measured for photon transverse energy > 15 GeV, and for separations between photons and final-state electrons in the pseudorapidity-azimuthal plane of ΔR(e, γ) > 0.7 in eeγ final state. A dielectron invariant mass requirement of di-electron pair > 50 GeV is imposed. The σ(pp → Zγ) × B(Z → e+ e−) is measured to be 5.20 ± 0.13(stat) ± 0.32(syst) ± 0.11(lum) pb. The results are consistent with predictions from the standard model.