In this thesis, we predict temperature of phosphor with fitting parameters of emission spectra, and investigate distribution of phosphor’s temperature with multiple package types. At the same time, we also analyze angular correlated color temperature deviation in this case. In the experiment, we choose pcW-LED of conformal coating type, and the severe high temperature condition was applied to the whole measurement duration, with recording the information of temperature, light intensity, spectrum and chromaticity. In addition, we utilize the parameter fitting of different spectra for each condition. Due to the heat source is varied with injection different currents, we can establish the database for spectral information. And we will compare two variables with different blue peak wavelengths and different phosphor’s thicknesses. Finally, in order to find the correspondence between the spectral characteristics and phosphor’s temperature, we select consistent region of wavelength to fit.