合成含氟苯并咪唑卡賓配位基的光敏染料運用於染料敏化太陽能電池

Synthesis of a photosensitizer with a fluorine containing benzimidazole carbene ligand for dye sensitized solar cell application

柯明鑫(Ming-shin Ke)

指導教授 ： 李文仁

國立中央大學/理學院/化學系/碩士(2011年)

摘要

本實驗室開發的N-Heterocyclic carbene-pyridine-based ruthenium染料結構，成功運用在染料敏化太陽能電池，在2010年發表在Angew. Chem. Int. Ed.，表現出高效率(η = 9.69%)，超越過去公認所使用的N719染料(η = 8.98%)。
本論文則是以此結構為主體，合成出其含氟的多電子衍生物，預期其光電轉換效率有更進一步的突破。

關鍵字

敏化染料太陽能電池

並列摘要

The development of N-heterocyclic carbine-pyridine-based ruthenium dye structure in our laboratory, the successful use in dye-sensitized solar cells was published in Angew. Chem. Int. Ed.in 2010, showing high efficiency (η = 9.69%) beyond the recognized of N719 dye (η = 8.98%) in the past.
Therefore, the main structure in this thesis is synthesized for the fluorine-containing derivative, which will expect to be good in the efficient performance.

並列關鍵字

dye-sensitized solar cells

參考文獻

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