This study prepare the TiO2 thick film by sol-gel method, discuss the relation between film thickness and photoelectric conversion efficiency. The result show that TPP ( tetraphenylporphine ) and Laser dye are used as dye respectively, to increase light absorb. In fact, the silver paste can enhance the photoelectric property, the energy conversion efficiency can increase more than 30 times. The best thickness of TiO2 thick film is about 4.5μm, the max efficiency of solar cell absorb Zn-TPP and R610 Chloride dye can attain 2.79﹪and 2.54.