In this study, the conductive copper wires, and stainless steel fibers were used as the warp yarns, and polyester fibers was used as the weft yarn, which fabricated a variety of the metallic woven fabrics by using hand loom. Changing the woven fabric structure, weft density, laminated ply and angle to investigate the electromagnetic shielding effectiveness and electrostatic discharge. From the experimental results, the EMSEE and ESD of the composites are increased with increasing fabric density, and the surface resisitivity is increased with decreasing the laminated ply. The resistivity of the composites is within the electromagnetic shielding materials.