The solution process was employed throughout this study to synthesis all the materials. With proper reductant, surfactant, precipitant and (-or) additive, nano-silver with various structures and semiconductor quantum dots as well can be successfully prepared.
In this work, water- and oil-based silver colloids were chemically synthesized by dextrose as reductant. In the presence of different surfactants silver colloidal particles with fine size and also narrow distribution can be prepared even under quite high concentration. The key is to prepare the insoluble silver salt as the precursor by reacting silver nitrate with urea and sodium hydroxide together in advance before final reduction reaction, by which we can techniquelly avoid the occurrence of instant reduction, and that hence give much time for surfactant molecules to adsorb onto the metal surface to help with well dispersion. By the similar approach Ag-Cu colloidal suspension can be obtained, and its conductive line has been experimentally demonstrated capable of restraining the electromigration. In addition, silver nanoparticles have the unique feature of surface plasmon resonance and are located on the single crystal silicon solar cell device by spin coating method, which has been showed the improvement of the energy conversion efficiency due to the enhanced absorption toward incident photons by silver. On the other hand, the far-infrared (FIR) radiation from a normal subtract can be effectively sheltered after coated with silver colloids on its surface, which shows the potential for silver colloids as an FIR stealth paint.
In the synthesis study on silver nanowires, the wires with quite large aspect ratio through an PVP polymer-mediated polyol process was fabricated. The key is to control the accumulation rate of silver ions in the system for the purpose of the formation of wires. During the process, the scale control of the product was achieved by tuning the concentration of either palladium or silver ions. Spreading the silver wires suspension by spraying method onto the transparent substrate can prepare a transparent conductive coating (TCC). The study shows that a coating with longer and thinner wires can give better transmittance performance due to lower deposition threshold for electrical conduction. Also, by following spray of the acrylic resin and then treating with proper baking and light-curing procedures can enhance the adhesive force of silver wires coating to substrate.
The nontoxic MPA capping ZnSe quantum dots (QDs) aqueous solution has been prepared by solution process. By tuning the process parameters the reasonable photoluminescence (PL) performance can be obtained. Hydrothermal treatment upon the above solution has been proved capable of help with the growth of QDs to obtain the property of longer excitation wavelength more than 350nm at least, which can pass through the object lens of a normal luminescence microscopy more effectively and hence make it easier to directly observe by human eyes. The following capping molecules replacement by MPS can form a net structure among the QDs to keep from agglomeration to help with stabilization for longer time. Further, in the Mn2+ doping ZnS QDs study, since Mn2+ ion solved in the ZnS lattice gives an PL center within the band gap of ZnS, tuning the composition to alter the relative intensity of bimodal PL peaks can obtain the multiple colors of PL. Also, by the means of doping route, CdPbS composite QDs with near infrared (NIR) emission wavelength around 830nm has been synthesized. The NIR emission was attributed to the defects in the heterogeneous interface during the preparation. NIR emission not only penetrates tissue more effectively but can avoid the disturbance of autoluminescence from the biological molecules. By coprecipitation method along with the proper processing means, the composition distribution inside the QDs that shows a well correlation with the PL intensity can be tunable.

1. 前言
2. 文獻回顧
2.1. 多結構形態金屬銀之合成
2.1.1. 球狀銀
2.1.2. 絲狀銀
2.2. 雙金屬合金微粒之合成
2.3. 金屬核殼結構粒子
2.4. 金屬奈米點於基板之佈位
2.5. 電遷移行為
2.6. 金屬塗料在遠紅外線遮蔽應用
2.7. 奈米金屬絲做為導電透明膜應用
2.8. 奈米半導體微粒於分子監控顯影應用
2.8.1. 奈米半導體微粒簡介
2.8.2. 分子監控顯影應用
2.8.3. 紅外線螢光發射量子點
3. 實驗方法
3.1. 實驗藥品與儀器
3.1.1. 藥品與耗材
3.1.2. 實驗儀器
3.2. 先前研究心得
3.3. 多重結構銀粒子合成機制與特性分析
3.3.1. 水溶性球狀銀製程
3.3.2. 油溶性球狀銀製程
3.3.3. 絲狀銀製程
3.4. 銀銅複合微粒製程
3.4.1. 銀銅膠體的製備
3.4.2. 線路繪製及電遷移測試
3.5. 二氧化矽-銀核殼結構粒子合成與特性分析
3.6. 金屬塗料的製備與遠紅外線性質檢測
3.6.1. 塗料製備
3.6.2. 薄膜之塗佈程序
3.6.3. 發射率量測
3.6.4. 附著性和腐蝕性測試
3.7. 奈米銀改善太陽電池效能
3.8. 透明導電薄膜製備流程
3.9. 添加銀絲於鎳鐵電池之製程
3.9.1. 銀絲/奈米鐵電極之製作
3.9.2. 銀絲/奈米鐵電極之電量測試
3.10. 近可見光激發無毒性量子點製備
3.11. 多種螢光顏色量子點製備
3.12. 近紅外光發射量子點製備
4. 結果與討論
4.1. 多重結構金屬粒子合成機制與特性分析
4.1.1. 水溶性球狀奈米銀
4.1.2. 油溶性球狀銀
4.1.3. 絲狀銀
4.1.4. 結論
4.2. 銀銅複合微粒製程
4.2.1. 銀銅複合微粒的製備與分析
4.2.2. 線路繪製及電遷移測試
4.2.3. 結論
4.3. 二氧化矽-銀核殼結構粒子合成與特性分析
4.3.1. 二氧化矽-銀核殼粒子製備
4.3.2. 二氧化矽-銀核殼結構粒子做為銀粒子佈位
4.3.3. 結論
4.4. 金屬塗料的製備與遠紅外線性質檢測
4.4.1. 由金屬填料及無機黏著劑組成之塗層發射率
4.4.2. 分離塗佈之程序
4.4.3. 附著性和腐蝕測試
4.4.4. 結論
4.5 奈米銀改善太陽電池效能
4.6. 銀絲/奈米鐵電極之電量測試
4.7. 奈米金屬絲做為導電透明膜
4.7.1. 銀絲塗層分析
4.7.2. 透明導電膜製膜程序
4.7.3. 結論
4.8. 近可見光激發量子點製備
4.8.1. 製程設計與性質檢測
4.8.2. 包覆劑配基的取代
4.8.3. 結論
4.9. 多種顏色螢光量子點製備
4.10. 近紅外光發射量子點製備
5. 總結
6. 參考文獻
7. 附錄
7.1. 個人研究經歷
7.1.1. 學歷
7.1.2. 海外研究經歷
7.2. 個人著作
7.2.1. 期刊論文
7.2.2. 會議論文
7.2.3. 專利
7.2.4. 其他著作
7.3. 硝酸鎘之毒性安全資料

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鹽水噴霧試驗裝置, 工業技術研究院系統與航太技術發展中心提供
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