本研究將傳統蒸餾總複合曲線(CGCC)的分析方法，應用於反應蒸餾塔熱整合效能分析：建議一套計算反應蒸餾塔總複合曲線時之關鍵設定方法，確立反應蒸餾總複合曲線之邊界的位置應為反應熱的位置，利用狹點與邊界的距離及反應在狹點上下之進行程度分辨反應熱是否有效被利用。
我們將此一分析方法應用於Al-Arfaj and Luyben 建議之ABCD理想溶液構成之反應蒸餾標準測試系統及甲基第三丁基醚(MTBE)反應蒸餾系統；發現在最佳化條件下，標準測試系統Ip, IIIp, IIIr 及MTBE 系統狹點與邊界的距離為極為接近，大部份的放熱反應在狹點以上進行，顯示反應熱有效被利用；標準測試系統Ir, 及IIr 大部份的放熱反應在狹點下進行，顯示這些系統不適合反應蒸餾；標準測試系統IIp, 雖然大部份的放熱反應都在狹點以上進行，但狹點與邊界的距離距離顯示反應熱未能有效被利用。

摘要-------------------------------------------------------I
目錄------------------------------------------------------II
表目錄----------------------------------------------------IV
圖目錄-----------------------------------------------------V

第一章 緒論
一.1 反應蒸餾介紹-----------------------------------1
一.2 文獻回顧---------------------------------------3
一.2.1:程序設計------------------------------------3
一.2.2:控制策略------------------------------------6
一.3 研究動機與章節安排-----------------------------7

第二章 蒸餾塔之總複合曲線(CGCC)
二.1 一般蒸餾塔CGCC之計算原理-----------------------9
二.2 反應蒸餾塔之計算原理--------------------------13

第三章 ABCD理想溶液反應蒸餾系統標準測試問題之CGCC分析
三.1 問題描述及命名--------------------------------18
三.2 熱力學與動力學模式----------------------------19
三.3 分析結果-- -----------------------------------20
三.3.1:Ip反應-------------------------------------20
三.3.2:Ir反應-------------------------------------22
三.3.3:IIp反應------------------------------------24
三.3.4:IIr反應------------------------------------26
三.3.5:IIIp反應-----------------------------------28
三.3.6:IIIr反應-----------------------------------30
三.4 結論------------------------------------------32

第四章 甲基第三丁基醚(MTBE)反應程序分析
四.1 甲基第三丁基醚簡介----------------------------34
四.2 反應及動力學----------------------------------35
四.3 流程及關鍵成份設定----------------------------36
四.4 CGCC分析--------------------------------------37
四.5 改善方案--------------------------------------38
四.6 結論------------------------------------------40

第五章 結論--------------------------------------------41

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