- 期刊
Use of Silyl Chlorides as Dimethyl Sulfoxide Activators for the Oxidation of Alcohols
以氯矽烷作為DMSO氧化醇類之活化劑
並列摘要
The investigation on the use of silyl chlorides as dimethyl sulfoxide activators for the oxidation of alcohols is described. Of a number of silyl chlorides examined, trimethylchlorosilane was found to be particularly useful as an activating agent for dimethyl sulfoxide in the Pfitzner-Moffatt oxidation of secondary alcohols; under conditions similar to those used for the Swern oxidation, the corresponding ketones were produced, in general, in satisfactory yields. This activator was however shown to be incompatible with primary alcohols, as the major process in most cases was silylation of the hydroxy group.
並列關鍵字
無資料延伸閱讀
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