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The Diatomic Rotating Vibrator According to Classical Mechanics

並列摘要


We compare the analytic results of solution of the radial equation of motion for a nonrotating or rotating diatomic molecule according to an anharmonic function for the internuclear potential energy with the corresponding quantal results. In this way we demonstrate that classical mechanics, in conjunction with the empirical quantal laws, can produce a comprehensive treatment of the frequencies and intensities of vibration-rotational transitions with at least semi-quantitative accuracy.

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