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如何解決蒸餾主塔迴流槽油水乳化和固體懸浮問題

How to Solve the Emulsion and Solid Suspension Problems in Reflux Drum

摘要


為配合製程和操作需要,操作人員常須要在煉製設備內注入相關學添加劑,例如:在蒸餾主塔的頂流系統中須注入薄膜式抗蝕劑和中和劑,以防止設備腐蝕。 大部分的化學添加劑為界面活性劑,由於其面活性作用,可以滿足製程和操作的需求,但是也因這些複合性能在不同的場合產生不一樣的組合作用,而會對下游設備的操作造成不良的影響。 本文詳細說明迴流槽油水乳化和固體粒子懸浮問題的可能原因;文中也提及解決蒸餾主塔迴流槽油水乳化和固體懸乳的補救辦法。在過去一段時間內進行的一些實驗結果也列示於文中,提供參考。 市面上,由於化學添加劑的廠牌繁多,而且使用的藥劑量又多不相同。如欲解決這些不良影響,必須根據實際狀況,分析問題所在,依實驗結果,予以解決。

並列摘要


The chemical additives are often injected into the refining processes to meet the requirements of the process operations. For instance, the filming corrosion inhibitors and the neutralizers are added into the overhead system of the main distillation tower of CDU to prevent the corrosion of the equipment internals. Most of the chemical additives are surfactants. Due to its' surface active functional properties,. the additives can satisfy the requirements of the operations, but, unfortunately, result in the adverse effects on the operations of the down stream equipments for the different chacteristic combinations of the composite properties of the additives at different locations. This article describes the probable causes for the W/O emulsions and the solid particles suspension problems happened in the reflux dram. The corrective measures to stop the emulsion and solid particles scespension are mentioned. Some results of the experiments conducted in the past few weeks are mentioned also. Hundreds of chemical additives have been developed in the markets. While they are applied in the refinery, the brands and the dosages of them are different from place to place. The ways to solve the adverse effects are always to analyze the problems with the laboratory tests and to deal with these problems according to the results.

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