Many studies indicated that brand awareness and brand image are directly related to brand loyalty. Brand managers primarily focus on how to improve customers' brand loyalty. This study investigates 503 consumers in domestic rice wine market and provides a brand loyalty model, adopting Structural Equation Modeling (SEM) to analysis the relationship among brand awareness, brand image, perceived risk and brand loyalty. The results indicate brand awareness and brand image would significantly positive affect brand loyalty, and consumers perceived risk would significantly negative affect brand loyalty. Besides, brand awareness and brand image would significantly reduce perceived awareness. The result indicates the enterprise should apply brand awareness and brand image to reduce customers' perceived awareness and raise brand loyalty.