Collaborative Search is a new social search concept that uses group collaboration to do this assistant job. Collaborative search provides a sharing space in Internet and allows people to solve their search problem together. People can learn from each other and guide less experienced members through their searches. Their search ability can also be improved by exchange knowledge in those social activities. In this study, we developed a Collaborative Search System and reported a case study of its influence on undergraduate students' information problem-solving when they search in Internet. Results showed that the collaborative search could help students' group search processes, improve their search outcomes and reduce difficulty in information retrieval. A measurement of students' search histories also indicated that their search skills and evaluation abilities were promoted by collaborative search.