- 期刊
全氟醯基過氧化物的單電子氧化機理及作為全氟烷基化試劑的合成應用
ET Reactions and Synthetic Applications of Per(poly) fluorodiacyl Peroxides
摘要
本文概述了含氟新試劑全(多)氟醯基過氧化物的合成、熱分解及其與富電子芳香族受物間的單電子轉移反應的機理，並對其中生成的芳香族陽離子基的結構碎片化途徑及其影響因素做了較深入的論述。還簡要地介紹了它作為對芳環、芳雜環、C_(60) 等的全氟烷基化試劑及烯烴聚合的引發劑在合成含氟功能化合物中的應用。
並列摘要
This article briefly describes the theory of Split-flow Thin (SPLITT) Fractionation techniques and reviews the recent developments and applications of various applied fields. SPLITT Fractionation is a new family of separation techniques for macromolecules, colloids, and particles. Various forces can be applied perpendicular to the thin channel for separation according to the physical properties of samples. The applied forces include electrical, gravitational, centrifugal, and magnetic forces. SPLITT fractionation is designed for preparative application with throughputs at several grams or subgrams per hour.
延伸閱讀
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