金屬高分子材料：聯吡啶和吡啶之應用

Materials of Metal-containing Polymers: Application of Bipyridine and Terpyridine Ligands

譚婉康(Uan-Kang Tan)

《化學》 63卷3期 (2005/09) Pp. 391-408

https://doi.org/10.6623/chem.2005033

摘要

過去數十年，混合無機和有機結構之金屬錯合物，在新材料研發上吸引科學家多方的重視。開發聯結這些含有金屬錯合物與大分子和超大分子而形成的材料，具有從基礎研究到光電應用許多不等之用途，這一切都是由於金屬與配位基的結合具有高度穩定度。所以近年來，許多科學家以過渡金屬與聯吡啶或三噙啶易形成穩定錯合物之特性，將其廣泛地運用在新材料的設計。故本文旨在，以聯吡啶和三吡啶為鉗合配位基之金屬聚合物，在新材料上應用加以描述和討論，並簡述未來之展望。

關鍵字

含金屬聚合物 ； 聯吡啶配位基 ； 三吡啶配位基

並列摘要

New inorganic-organic hybrid structures based on metal complexes have become of increasing interest over the last few decades in the search for new materials. The combination of macromolecular and supramolecular chemistry has been attempted by developing metal-complexing and metal-containing polymers for a wide variety of applications that range from basic science to advanced optoelectronic materials. The stability of the metal-containing polymers is a fundamental requirement for such applications. In this respect, using bi- and terpyridines as chelating ligands is highly promising because when these molecules combine with transition metals are known as the highly stable complexes and with interesting physical properties. During the last few years, many efforts have been made to the novel materials along with their intelligent and the tunable properties from the self-assembling to the supramolecular polymers. Here is the overview of metal-containing polymers based on using bipyridine and terpyridine as chelating ligands and their potential application towards new materials.

並列關鍵字

metal-containing polymers ； bipyridine ligands ； terpyridine ligands