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鋅以外之過渡金屬在乳酸交酯的開環聚合催化反應

Ring-Opening Polymerization of Lactides Catalyzed by Transition Metals Except Zn

摘要


近年來由於環境污染與石油危機,科學家積極尋找替代石化塑膠的原料,使得乳酸交酯的開環聚合催化反應形成很熱門研究領域。因為過渡金屬的多元性,使用過渡金屬催化劑的比例也很高。所以本文將文獻中有關過渡金屬催化劑應用於乳酸交酯的開環聚合催化反應加以歸納整理,分析過渡金屬各族的特色與實驗結果。也將所使用的配位基加以分類,提供給讀者作為參考。

並列摘要


Recently because of the environmental pollution and oil crisis, the scientists study the new material positively, especially ring-opening polymerization (ROP) of lactides to substitute for the petrochemical plastics. Moreover, the proportion of using transition metal catalysts is high on account of the diversification of transition metal. In this article, the literatures of the lactides ROP with transition metal catalysts were reorganized by group characters, classification of ligands and experiment results to be available to readers as references.

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