3D electronics packaging and heterogeneous integration technologies have been widely discussed and developed in recent years. High aspect ratio (HAR) through glass via (TGV) substrate is one option as an interposer substrate. Glass substrate provides several advantages, such as low dielectric constant, ultra-high resistivity, high dimensional stability, low coefficient of thermal expansion (CTE) mismatch with copper (Cu) material, and good mechanical properties. However, the Cu metallization for HAR TGV with defect-free filling is challenged by using a simple all-solution process. In this study, we demonstrated a defect-free Cu filling for HAR TGVs by an all-solution process. Furthermore, this TGV is filled by novel DC plating in presence of a single additive formula under a stagnant condition without forced convection.