利用有限差分法研究向列型液晶分子於具微溝槽結構的表面上之排列行為

The study of the alignment of nematic liquid crystals on grooved contour by finite difference method

陳姿穎(Tzu-Ying Chen)

指導教授 ： 陳立仁

共同指導教授 ： 陸駿逸(Chun-Yi Lu)

國立臺灣大學/工學院/化學工程學研究所/碩士(2008年)

https://doi.org/10.6342/NTU.2008.01410

摘要

無資料

關鍵字

預傾角 ； 錨附能 ； 液晶 ； 方位角

並列摘要

In this study, modeling liquid crystals align on a specific groove system is realized. The Oseen-Frank Equation and Rapini-Papoular form are used respectively for the bulk energy and surface energy of liquid crystal molecules. Making use of calculus of variations, we first deduce the govern equation and its corresponding boundary conditions. By means of finite difference method to investigate this problem, we can visualize the alignment of the directors in the semi-finite medium. Different from lots of previous research, the contour of the substrate can be arbitrary theoretically. A more generalized form of surface energy is introduced in our calculation. Thus, the angle related to the surface energy doesn’t need to be very small any longer. We also can derive the exact azimuthal angle in space.
The surface polarity can control the azimuthal angle strongly. As the polarity is strong enough, the director will align along the groove direction. While discussing how the free energy varies with the strength of anchoring, we can label the critical weak anchoring to be 10-4J/m2. Under very weak anchoring, the relationship between free energy and anchoring strength is linear and passes through the origin. Furthermore, various geometries are tuned to discuss the alignment in this study.
This result may provide useful guidelines for variable liquid crystal pretilt angle control on a grooved substrate.

並列關鍵字

pretilt angle ； anchoring ； liquid crystal ； azimuthal angle ； groove

參考文獻

Abbott M. B., Basco D. R., Computational fluid dynamics: an introduction for engineers, (Longman,1989)

Berreman D.W., Phys. Rev. Lett. 28, 1683 (1972)

Berreman D.W., Mol. Cryst. 23, 215 (1973)

Chatelain P., Bull. Soc. Fr. Miner. 66, 105 (1943)

Chiou D. R., Chen L. J., Langmuir 22, 9403 (2006)