(a) 可回收含氟鉑金屬催化劑催化Hydrosilation之研究 (b) 新型含氟鉑金屬錯合物合成與鑑定

(a) Recyclable Polyfluorinated Platinum Metal Complex catalyzed Hydrosilation reaction. (b) Novel Polyfluorinated Platinum metal complex Synthesis and Characterization.

鐘威丞(Wei-cheng chung)

指導教授 ： 呂良賜

國立臺北科技大學/工程學院/有機高分子研究所/碩士(2014年)

https://doi.org/10.6841/NTUT.2014.00579

摘要

(a) [PtCl2(5,5’-bis(RfCH2OCH2)-2,2’-bpy)](Rf=C11F23)已經被成功合成出來，在這篇論文裡將會展示[PtCl2(5,5’-bis(RfCH2OCH2)-2,2’-bpy)](Rf=C11F23)用來催化hydrosilation的反應效果和回收重複使用的能力，從結果來看含有長氟鏈的[PtCl2(5,5’-bis(RfCH2OCH2)-2,2’-bpy)](Rf=C11F23)熱穩定性佳且催化效果良好，也成功達到回收使用的目的。

(b) 以[PtCl2(5,5’-bis(CF3CH2OCH2)-2,2’-bpy)]作為起始物導入新的螯合基成為新型含氟鉑金屬錯合物，合成方法為使用銅催化反應進行。主要目的是期望透過新導入的螯合基增加含氟鉑金屬錯合物的應用，新合成出的錯合物使用NMR（1H、13C、19F）、IR、高解析質譜儀HR-MS(FAB)、X-ray單晶繞射儀來鑑定這些錯合物。

關鍵字

鉑金屬錯合物 ； hydrosilation

並列摘要

(a) [PtCl2(5,5’-bis(RfCH2OCH2)-2,2’-bpy)](Rf=C11F23) has been successfully synthesized. This paper will show the effect of [PtCl2(5,5’-bis(RfCH2OCH2)-2,2’-bpy)](Rf=C11F23) to catalyze hydrosilation reaction and ability to be recycled for reuse. From the results, [PtCl2(5,5’-bis(RfCH2OCH2)-2,2’-bpy)](Rf=C11F23) is good at thermal stability and the catalytic effect, also successfully used for the purpose of recycling.

(b) We use [PtCl2 (5,5 '-bis (CF3CH2OCH2) -2,2'-bpy)] as a starting material, introduced the new ligand to replace the chlorid to become the new metal complexes of platinum. Copper is used for the synthesis of catalytic reaction. Our main purpose is to increase the fluorinated platinum metal complexes the application through new chelating group introduced. New platinum metal using NMR , IR, high-resolution mass spectrometry , X-ray single crystal diffraction to identify these complexes.

並列關鍵字

hydrosilation ； platinum complex

參考文獻

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