Generally, the efficiency of the electron-injection process is strongly dependent on the bonding structure of the dye molecules absorbed on the TiO2 film. In addition, electron transfer in the DSSC is strongly affected by the electrostatic and chemical interactions between the TiO2 surface and the absorbed dye molecules. The TiO2 film usually need to coat more than twice. In order to let dye molecules suffieiently absorbed on the TiO2 film, it usually immerse the film into the dye solution more than 8 hours. We have successfully demonstrated that the electrospun photoanode could provide a competitive alternative to the fabrication of DSSCs with less time and lower cost. We believe the simple and cheap merits of electrospinning will increase its potential in DSSCs and help them move to commercialisation quickly. The overall conversion efficiency of DSSC with photoanode prepared by the electrospun process showed slightly lower than that of conventional process.