DNPH與Cu(II)反應的動力學及反應機制探討

Kinetics and Mechanism of 2,4-Dinitrophenylhydrazine (DNPH) with Copper(II)

古冠軒(Kuan-Hsuan Ku)

指導教授 ： 吳劍侯

國立清華大學/原子科學院/生醫工程與環境科學系/碩士(2007年)

https://doi.org/10.6843/NTHU.2007.00525

摘要

無資料

關鍵字

2,4-dinitrophenylhydrazine ； 銅錯合物 ； 動力學 ； 反應機制

並列摘要

無資料

並列關鍵字

2,4-dinitrophenylhydrazine ； copper complexes ； kinetics ； mechansism

參考文獻

Achatz, S.; Lörinci, G.; Hertkorn, N.; Gebefügi, I.; Kettrup, A.,Disturbance of the determination of aldehydes and ketones: Structural elucidation of degradation products derived from the reaction of 2,4-dinitrophenylhydrazine (DNPH) with ozone. Fresenius Journal of Analytical Chemistry 1999, 364, 141-146.

Atkinson, R.; Carter, W. P. L.,Kinetics and mechanisms of the gas-phase reactions of ozone with organic compounds under atmospheric conditions. Chemical Reviews 1984, 84, 437-470.

Banerjee, S.; Jr., E. J. P.; Sikka, H.; Kelly, C. M.,Kinetics of oxidation of methylhydrazine in water. Factors controlling the formation of 1,1-dimethylnitrosamine. Chemosphere 1984, 13, 549-559.

Bernheim, P.; Dobos, A.; Doherty, A. M. M.; Haine, N.; Stedman, G.,Kinetics and mechanism of the reaction of nitrous acid with 2,4-dinitrophenylhydrazine. Journal of the Chemical Society, Perkin Transactions 2 1996, 275-280.

Besada, A.,Analytical use of copper(II)-neocuproine in the spectrophotometric determination of hydrazines. Analytical Letters 1988, 21, 1917-1925.