含N,N'-二-(4-吡啶)己二醯二胺配位基與二價鋅及鎘金屬化合物之合成,結構與特性研究

Synthesis, Structures and Properties of Znic(II) and Cadmium (II) Complexes Containing N-N'-di-(4-pyridyl)adipoamide Ligand

張尹瑞(Yin-Jui Chang)

指導教授 ： 陳志德

中原大學/理學院/化學研究所/碩士(2011年)

https://doi.org/10.6840/cycu201100573

摘要

本論文中以N,N'-二-(4-吡啶)己二醯二胺(L)或4-胺基吡啶(4-apy)分別和4,4’-醚基二苯甲酸(H2OBA)與4,4’-磺醯基二苯甲酸(H2SDA)混合，利用中溫水熱法與鋅(II)、鎘(II)金屬鹽類反應，合成出六個新型配位聚合物，它們分別為：{[Zn(OBA)(L)] • 2H2O}∞ (1)、{[Zn(SDA)(L)] • 2H2O}∞ (2)、{[Cd(OBA)(L)] • 2H2O}∞ (3)、{[Cd(SDA)(L)] • H2O}∞ (4)、[Cd(OBA)(4-apy)2]∞ (5)、[Cd(OBA)(H2O)2]∞ (6)。以上化合物除了以單晶X-ray繞射儀來鑑定其單晶結構外，並利用粉末X-ray繞射分析、元素分析、熱重分析、紅外光光譜來研究化合物特性。化合物1與3為一維的螺旋孔洞，彼此間利用連鎖的方式形成1D→2D多聚連鎖糾纏結構。化合物2與5，結構皆為一維的鏈狀結構，化合物2利用O-H---O的氫鍵作用力形成二維的層狀結構，化合物5則是利用N-H---O的氫鍵作用力形成二維的層狀結構。化合物4之中心金屬為六配位些微扭曲的三角棱柱構型，其結構為一個具有2-節點(2,4)-連接(4)(4•85)的二維層狀拓譜結構，層狀結構間以平行的方式相互貫穿，形成一個2-fold交互貫穿的結構。化合物6為七配位扭曲的雙五角錐構型，結構可看出為一個3-節點(2,4)-連接(12)(12)(126)的三維網狀結構。

關鍵字

鋅 ； 鎘 ； N-N'-二-(4-吡啶)己二醯二胺配位基

並列摘要

This thesis discusses the chemistry of zinc(II) and cadmium(II) complexes containing mixed ligands of N,N'-di(4-pyridyl)adipoamide (L), 4-aminopyridine (4-apy), 4,4’-oxybis(benzoic acid) (H2OBA) or 4,4’-sulfonyldibenzoic acid (H2SDA). The hydrothermal reactions of these four ligands with Zn(OAc)2, ZnBr2 and CdBr2 • 4H2O afforded six complexes {[Zn(OBA)(L)] • 2H2O}∞, (1), {[Zn(SDA)(L)] • 2H2O}∞, (2), {[Cd(OBA)(L)] • 2H2O}∞, (3), {[Cd(SDA)(L)] • H2O}∞, (4), [Cd(OBA)(4-apy)2]∞, (5), [Cd(OBA)(H2O)2]∞, (6). All complexes have been characterized by EA, IR, TGA and Powder X-ray diffraction and structurally characterized by X-ray crystallography. In complexes 1 and 3, the 1D helical channels are polycatenated to form 2D nets. The 1D looped chains of 2 are interlinked through O-H---O hydrogen bonds whereas the 1D linear chains of complexes 5 are interlinked through N-H---O hydrogen bonds to form 2D supramolecular structures. The Cd(II) ions of 4 are linked by the ligans to form 2D nets with a topology of (4)(4•85), which are 2-fold interpenetrated to form a 2D network. In complex 6, the cadmium(II) cations are linked by the ligans to form a 3D network with a topology of (12)(12)(12)6

並列關鍵字

Zinc ； Cadmium ； N-N'-di-(4-pyridyl)adipoamide Ligand

參考文獻

8. M. B. Zaman, M. D. Smith, D. M. Ciurtin, H.-C. Zur Loye, Inorg. Chem.2002, 41, 4895.

1. K. Biradha, A. Ramanan, J. J. Vittal, Cryst. Growth Des. 2009, 9, 2969.

3. H. J. Choi, M.P. Suh, Inorg. Chem. 1999, 38, 6309.

5. G. De Munno, D. Armentano, T. Poerio, M. Julve, J. A. Real, J. Chem. Soc.Dalton Trans. 1999, 1813.

6. G.-P. Yong, Z.-Y. Wang, Y. Cui, Eur. J. Inorg. Chem. 2004, 21, 4317.