The view of emotion was a human evolutionary leftover from animal defects for psychology. Until recently, science knows that the human’s posses for emotion was an evolutionarily, emotions play a critical role in daily live, helping assess situations as good or bad, safe or dangerous. There are numerous studies about emotion issues. Psychologists Isen, Davidson and Norman point out — positive/negative emotions are critical to perception, learning, and creative thought. Recently, the web-based learning products grow up with cyberspaces, emotions stimulating in the online environment is especially important because communication scheme in the Internet assess learning process validity via user’s affection. In this study, emotional researches and the relevance between emotional inductions and learning process were reviewed. Firstly, by applying protocol analysis abstracting materials of semi-structured interviews from professionally e-instructional designer and six emotional inductions were obtained from transcriptions coding. The results from the first study indicated that highly relevance between emotional inductions and learning process. Secondly, the result was adopted to design a Web-based arts learning framework. Finally, six emotional inductions and framework coupled with the aesthetics of interaction were integrated and five Web-based art knowledge exploring systems were demonstrated.