The contact characteristics of the Ag/n-GaSb diode were discussed in the paper. As the diode was prepared, it was annealed by rapid thermal annealing system at various of temperature. A best diode characteristic was obtained at 350 ˚C for 45 sec and showed a saturation current density of 1.29×10-3 A/cm2, a Schottky barrier height of 0.51 eV with an ideality factor of 1.39. The series resistance was 4.56 KΩ which was evaluated by Norde function. As the annealed temperature was increased to 400 ˚C, both the ideality factor and reverse leakage current was increased. For a further discussion of the electrical characteristics, the Cheung’s function was also used to evaluate the barrier height and ideality factor of the diode.