Highly sensitive surface acoustic wave (SAW) humidity sensors have been fabricated by spin-coating polyvinyl-alcohol (PVA) thin film on the SAW resonators. The transmission properties of the SAW sensor, including center frequency and insertion loss will be studied at a relativity humidity ranging from 30 to 90%. Frequency deviation of 1517 KHz and insertion loss deviation of -10.31 dB are obtained when the PVA thin film thickness has been increased to about 3000Å in the variation of relative humidity. The short-term repeatability and the hysteresis of water absorption and desorption cycle will be examined. The results have justified the suitability for the PVA film coated SAW resonators in the application of sensing humidity at a higher relative humidity.