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硫酸對Fenton程序去除染料的影響

Effect of Sulfuric Acid on the Dye Degradation of Fenton Process

摘要


本研究使用RB19染料廢水,以Fenton程序進行染料去除反應,在不同鐵鹽作用下,加入硫酸根陰離子比較其去除效果,實驗以250 ml錐形瓶,在恆溫振盪器為之,溫度維持在30℃,轉速設定在160rpm,過氧化氫、鐵鹽、硫酸及氧化時間為操作變數。實驗結果顯示,Fenton氧化程序去除染料效果良好,且在相同加藥量下,硫酸亞鐵去除染料效果優於硫酸亞鐵銨;比較硫酸的影響,對於硫酸亞鐵銨負影響大於硫酸亞鐵。

關鍵字

Fenton程序 染料廢水 硫酸

並列摘要


The water sample synthetic RB19 was investigated for the removal of dye as function of ferric-salt and sulfuric acid during Fenton degradation in this study. The experiments were conducted in 250-ml flasks, which were capped and shaken in a isothermal oscillator tank with oscillation speed set at 160 rpm. The dosages of H2O2, ferric-salt, sulfuric acid and oxidation time are the operate parameters. These results show degradation in the Fenton process are feasible. The efficiency was in the order FeSO4•7H2O>FeSO4(NH4)2SO4•6H2O. The FeSO4(NH4)2SO4•6H2O has larger negative effect for sulfuric acid dosage.

並列關鍵字

Fenton process dye wastewater sulfuric acid

參考文獻


游非庸、黃媛禎、黃惠蓉(2008)。硫酸對Fenton程序脫色的影響。蘭陽學報。2008(6)
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De Laat, J.,Le, G. T.,Legube, B.(2004).A Comparative Study of the Effects of Chloride, Sulfate and Nitrate Ions on the Rates of Decomposition of H2O2 and Organic Compounds by Fe(II)/H2O2 and Fe(III)/H2O2.Chemosphere.55,715-723.
Ince, N. H.,Gonenc, D. T.(1997).Treatability of a Textile Azo Dye by UV/H2O2.Environ. Technol..118,179-185.

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