聚對苯二甲酸乙二酯／聚對苯二甲酸丙二酯摻合體熱裂解行為之探討

本實驗以不同重量比例聚對苯二甲酸乙二酯（ Polyethylene terephthalate ）和聚對苯二甲酸丙二酯（Polytrimethylene terephthalate）進行摻混形成一系列PET/PTT摻合體，以熱重分析儀（Thermalgravimetric analyzer）探討摻合體之熱裂解行為，再以Doyle-Ozawa積分法計算摻合體之裂解活化能。實驗結果顯示，PET／PTT摻合體熱裂解溫度隨著PTT含量的增加有往低溫偏移的趨勢，摻合體的裂解活化能皆介於兩個均聚物之間。

關鍵字

摻合體；裂解活化能

並列摘要

This study was focused on thermal degradation behavior of PET/PTT polymer blends, which were blended with different weight ratios of PET and PTT homopolymers. Thermal degradation behavior was observed using a Thermogravimetric Analyzer (TGA). The degradation activation energy was calculated by a Doyle-Ozawa equation. The results showed that the thermal degradation temperature of the blended PET/PTT decreased with an increase of PTT content. In addition, the degradation activation energies of the PET/PTT polymer blends were between that of two homopolymers.

並列關鍵字

Blends ； degradation activation energy ； Doyle-Ozawa equation

延伸閱讀

許祐鈞、蔣宗勳、高健峰、柯寰傑、石天威（2018）。聚對苯二甲酸乙二酯-co-聚萘二甲酸乙二酯共聚酯熱裂解動力學之探討。紡織綜合研究期刊，28(3)，12-21。https://doi.org/10.6439/TTRJ.201807_28(3).0002
楊沛萁（2012）。聚對苯二甲酸乙二酯/己二酸(0.075莫耳比)/聚乙二醇三組份共聚合體物性之研究〔碩士論文，國立臺北科技大學〕。華藝線上圖書館。https://doi.org/10.6841/NTUT.2012.00112
周瑞美（1998）。對苯二甲酸、乙二醇與丁二醇共聚酯結晶行為研究〔碩士論文，元智大學〕。華藝線上圖書館。https://www.airitilibrary.com/Article/Detail?DocID=U0009-0112200611301214
陳嘉政（1995）。聚對苯二甲酸二乙酯/聚醚亞醯摻合的相容性及結晶行為〔碩士論文，元智大學〕。華藝線上圖書館。https://www.airitilibrary.com/Article/Detail?DocID=U0009-0112200611323023
Sachdeva, S., & Kumar, A. (2010). Preparation and Characterization of Copolymer of Benzene and Perylene Photoluminescence Organic Material. Research Journal of Applied Sciences, Engineering and Technology, 2(6), 589-591. https://www.airitilibrary.com/Article/Detail?DocID=20407467-201009-201411050018-201411050018-589-591

國際替代計量

聚對苯二甲酸乙二酯／聚對苯二甲酸丙二酯摻合體熱裂解行為之探討

全文下載

主題瀏覽