- 期刊
- OpenAccess
Accessing the Impact of Sea-Salt Emissions on Aerosol Chemical Formation and Deposition over Pearl River Delta, China
並列摘要
Sea-salt aerosol (SSA) emissions have a significant impact on aerosol pollution and haze formation in the coastal areas. In this study, the Models-3/CMAQ modeling system was utilized to access the impact of SSA emissions on aerosol chemical formation and deposition over Pearl River Delta (PRD), China in July 2006. More SSAs were transported inland from the open-ocean under the southeast wind in summertime. Two experiments (with and without SSA emissions in the CMAQ model) were set up to compare the modeling results with each other. The results showed that the increase of sulfate concentrations was more attributable to the primary emissions of coarse SO_4^(2-) particles in SSA, while the increase of nitrate concentrations were more attributable to secondary chemical formations, known as the mechanisms of chloride depletion in SSA. In the coastal areas, 17.6 % of SO_4^(2-), 26.6% of NO_3^- and 38.2% of PM10 concentrations were attributed to SSA emissions, while those portions were less than 1% in the inland areas. The increases of PM10 and its components due to SSA emissions resulted in higher deposition fluxes over PRD, particularly in the coastal areas, except for the wet deposition of nitrate. Nitrate was more sensitive to SSA emissions in chemical formations than sulfate and dry deposition of aerosol was also more sensitive than that for wet deposition. Process analysis of sulfate and nitrate was applied to find out the difference of physical and chemical mechanisms between Guangzhou (the inland areas) and Zhuhai (the coastal areas). The negative contributions of dry deposition process to both sulfate and nitrate concentrations increased if SSA emissions were taken into account in the model, especially in Zhuhai. The negative contributions of cloud process also increased due to cloud scavenging and wet deposition process. In the coastal area, the gas-to-particle conversions became more active with high contributions of aerosol process to nitrate concentrations.
延伸閱讀
- Liu, B., Gong, W., Ma, Y., Zhang, M., Yang, J., & Zhang, M. (2018). Surface Aerosol Optical Properties during High and Low Pollution Periods at an Urban Site in Central China. Aerosol and Air Quality Research, 18(12), 3035-3046. https://doi.org/10.4209/aaqr.2017.12.0565
- Niu, J. (2010). A comprehensive analysis of terrestrial hydrological processes over the Pearl River basin in South China [doctoral dissertation, The University of Hong Kong]. Airiti Library. https://www.airitilibrary.com/Article/Detail?DocID=U0029-1812201200018550
- Xu, C., Duan, J., Wang, Y., Li, M., Cheng, T., Wang, H., Zhu, H., Xie, X., Liu, Y., Ling, Y., Li, X., Kong, L., He, Q., Wang, H., & Zhang, R. (2018). Effects of Wintertime Polluted Aerosol on Clouds over the Yangtze River Delta: Case Study. Aerosol and Air Quality Research, 18(7), 1799-1816. https://doi.org/10.4209/aaqr.2017.09.0322
- Lai, S., Ho, K., Zhang, Y., Lee, S., Huang, Y., & Zou, S. (2010). Characteristics of Residential Indoor Carbonaceous Aerosols: A Case Study in Guangzhou, Pearl River Delta Region. Aerosol and Air Quality Research, 10(5), 472-478. https://www.airitilibrary.com/Article/Detail?DocID=16808584-201010-201011240030-201011240030-472-478
- Xiao, Z. Y., Jiang, H., Zhou, G. M., Chen, J., & Zhang, R. J. (2013). Characteristics of Aerosol Optical Thickness as Well as the Relationship with NDVI in the Yangtze River Delta, China. Terrestrial, Atmospheric and Oceanic Sciences, 24(5), 863-876. https://doi.org/10.3319/TAO.2013.05.02.01(A)