- 期刊
TPGDA/SR-444/VTES/ZnO有機／無機奈米複合材料合成與性質之研究
Studies on Synthesis and Properties of TPGDA/SR-444/VTES/ZnO Organic/Inorganic Nanocomposites
摘要
本研究是利用溶膠－凝膠法製備具耐熱性佳、高透光性、UV遮蔽性及符合抗靜電範圍之TPGDA/SR-444/VTES/ZnO奈米複合材料。首先將VTES經pH1.5～2.5酸性水溶液水解能得到矽醇中間物，再添加無機金屬微粒ZnO能經由有機化改質反應順利共價鍵結至有機基材上，接著將此VTES/ZnO複合物利用剩餘的活性Si-OH或Zn-OH官能基與SR-444有機壓克力單體上的活性羥基行縮合脫水反應，合成出SR-444/VTES/ZnO複合物，最後添加TAIC架橋劑及TPGDA單體與SR-444/VTES/ZnO複合物行自由基光共聚合反應產生理想程度的網狀共價鍵結結構。
並列摘要
This research is to synthesis TPGDA/SR-444/VTES/ZnO nanocomposite materials with good high heat resistance, good transparence in visible, UV-shielding and anti-static properties by sol-gel reaction. Firstly, the VTES was performed the silanol intermediates by hydrolysis in pH1.5~2.5 acid solution. The inorganic fillers of powder ZnO could be successfully coupled and crosslinked to organic matrices. Afterwards, the active Si-OH or Zn-OH functional groups remained on the VTES/ZnO complexes that could be covalently bonding with SR-444 acrylate monomer. Finally, TPGDA,TAIC, and SR-444/VTES/ZnO complexes were covalently bonded by UV-activated free radical polymerization to achieve cross linked structure of organic/inorganic nanocomposite.
延伸閱讀
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- 鍾裕隆（2007）。CNTs-ZnO奈米複合材製備與特性分析〔碩士論文，國立臺北科技大學〕。華藝線上圖書館。https://doi.org/10.6841/NTUT.2007.00093
- Liu, J. Y. (2011). 奈米Au-Pd/CeO2/MWCNTs混成材料之合成與特性研究 [master's thesis, Tatung University]. Airiti Library. https://www.airitilibrary.com/Article/Detail?DocID=U0081-3001201315111036
- 楊雲玠（2007）。有機/無機混成製備奈米光學複合材料之研究〔碩士論文，國立中央大學〕。華藝線上圖書館。https://www.airitilibrary.com/Article/Detail?DocID=U0031-0207200917344073
- Wang, Y. L., Chen, J. H., Lu, S. B., & Lin, J. Y. (2020). Studies on Preparation and Properties of PGDA/GMA/MSMA/TiO_2 Organic/Inorganic Nanocomposites. International Journal of Uncertainty and Innovation Research, 2(3), 265-282. https://www.airitilibrary.com/Article/Detail?DocID=P20190619001-202012-202011240005-202011240005-265-282