本文之研究,以含有二羧酸氨基苯的有機配子 5-((pyridin-4-yl)methyleneamino)benzene-1,3-dicarboxylic acid (pmbd)與過渡金屬離子(CuII,ZnII)及以有機配子之鉀鹽potassium 5-((pyridin-4-yl)methyleneamino)benzene-1,3-dicarboxylate (ppmbd) 與過渡金屬離子(NiII, ZnII, MnII),在溫度調控環境下,進行自組裝合成,製備有機-無機金屬之配位聚合物。 第一部分,利用過渡金屬離子(CuII,ZnII)與有機配子pmbd以水浴法合成,分別得到三維結構{[Cu4Cl2(abd)2(OH)2]
In this thesis, 5-((pyridin-4-yl)methyleneamino)benzene-1,3-dicarboxylic acid was used as a ligand to react with transition-metal ions, and potassium 5-((pyridin-4-yl)methyleneamino)benzene-1,3-dicarboxylate was used as ligand to react with transition-metal ions under temperature control conditions. It is focussed on using the self-assembly synthesis, to prepare the metal organic coordination polymers. The first part of this report, the synthesis of transition-metal ions with pmbd ligand under hydrothermal conditions, respectively. A 3D MOF of {[Cu4Cl2(abd)2(OH)2]
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